Colloidal Crystals of Spheres and Cubes in Real and Reciprocal Space

von Janne-Mieke Meijer

155 Seiten, Hardcover

Kurzbeschreibung des Verlags

This thesis presents an in-depth study on the effect of colloidal particle shape and formation mechanism on self-organization and the final crystal symmetries that can be achieved. It demonstrates how state-of-the-art X-ray diffraction techniques can be used to produce detailed characterizations of colloidal crystal structures prepared using different self-assembly techniques, and how smart systems can be used to investigate defect formation and diffusion in-situ. One of the most remarkable phenomena exhibited by concentrated suspensions of colloidal particles is the spontaneous self-organization into structures with long-range spatial and/or orientational orders. The study also reveals the subtle structural variations that arise by changing the particle shape from spherical to that of a rounded cube. In particular, the roundness of the cube corners, when combined with the self-organization pathway, convective assembly or sedimentation, was shown to influence the final crystal symmetries.

• Reihe: Springer Theses
• ISBN: 9783319148083
• Sprache: Englisch
• Erscheinungsdatum: 27.06.2015
• Genre: Physik, Astronomie/Atomphysik, Kernphysik
• Verlag: Springer International Publishing